2-Anilino-4,6-dimethylpyrimidinium chloroacetate
نویسندگان
چکیده
In the crystal structure of the title compound, C(12)H(14)N(3) (+)·C(2)H(2)ClO(2) (-), the chloro-acetate anion is linked to the N-(4,6-dimethyl-pyrimidin-2-yl)aniline cation by N-H⋯O hydrogen bonding. Within the cation, the pyrimidine ring is twisted with respect to the phenyl ring by a dihedral angle of 7.59 (4)°.
منابع مشابه
2-Amino-4,6-dimethylpyrimidinium chloroacetate
There are two cations and two anions in the asymmetric unit of the title compound, C(6)H(10)N(3) (+)·C(2)H(2)ClO(2) (-). In the crystal, the components are linked by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds to form a two-dimensional network. Additional stabilization is provided by weak inter-molecular C-H⋯O inter-actions.
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In the crystal structure of the title compound, C(6)H(10)N(3) (+)·H(2)PO(4) (-), the cations and anions are linked by inter-molecular O-H⋯O and N-H⋯O hydrogen bonds, forming a two-dimensional network. Additional stabilization is provided by weak inter-molecular C-H⋯O inter-actions. N-H⋯N inter-actions are also present.
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In the title compound, C(6)H(10)N(3) (+)·C(7)H(3)N(2)O(6) (-)·2H(2)O, the amino-pyrimidine mol-ecule is protonated at one of the pyrimidine N atoms. The carboxyl-ate group of the 3,5-dinitro-benzoate anion inter-acts with the protonated pyrimidine N atom and the 2-amino group through a pair of N-H⋯O hydrogen bonds, forming an R(2) (2)(8) motif. Two inversion-related pyrimidine rings are linked ...
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In the title mol-ecule, C(24)H(23)Cl(2)N(3)O(7), the central benzene ring forms dihedral angles of 65.71 (1) and 44.42 (1)° with the pyrimidine ring and the terminal benzene ring, respectively. In the crystal, molecules are linked via C-H⋯O hydrogen bonds.
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Two non-innocent 2-anilino-4,6-di-tert-butylphenol units were connected through an -ortho bridging S atom and provided the ligand . The ligand reacted with CuCl2·2H2O in the presence of Et3N under air and generated a mononuclear Cu(ii) complex (1, [CuL(S(IBQ/ISQ))Cl](0)). A single crystal X-ray diffraction analysis confirmed that in the complex one of the two 2-anilido-4,6-di-tert-butylphenol a...
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